In cold regions on earth, negative temperatures on the Fahrenheit or Celsius scale can often occur in winter; in physics, however, they were so far impossible. On the absolute temperature scale that is used by physicists and also called Kelvin scale, one cannot go below zero – at least not in the sense of getting colder than zero Kelvin. According to the physical meaning of temperature, the temperature of a gas is determined by the chaotic movement of its particles – the colder the gas, the slower the particles. At zero Kelvin (-460°F or -273°C) the particles stop moving and all disorder disappears. Thus, nothing can be colder than absolute zero on the Kelvin scale. Physicists of the Ludwig-Maximilians University Munich and the Max Planck Institute of Quantum Optics in Garching have now created an atomic gas in the lab that has nonetheless negative Kelvin values. These negative absolute temperatures lead to several striking consequences: Although the atoms in the gas attract each other and give rise to a negative pressure, the gas does not collapse – a behavior that is also postulated for dark energy in cosmology. Also supposedly impossible heat engines can be realized with the help of negative absolute temperatures, such as an engine with a thermodynamic efficiency above 100%.
Negative Absolute Temperature for Motional Degrees of Freedom
by S. Braun, P. Ronzheimer, M. Schreiber, S. S. Hodgman, T. Rom, I. Bloch, U. Schneider
Science 339, 52 4. Januar 2013 doi: 10.1126/science.1227831
http://www.sciencemag.org/content/339/6115/52
Atoms at negative absolute temperature – the hottest systems in the world
http://www.quantum-munich.de/fileadmin/media/media/Negative_Temperature/Negative_absolute_Temperatur-EN-3.1.13.pdf
With negative temperatures an engine’s efficiency can be higher
Matter at negative absolute temperature leads to a whole bunch of astounding consequences: With its help, one could create heat engines with an efficiency above 100%. This does not mean that the law of energy conservation is violated. Instead, the machine could not only absorb energy from the hotter substance, but, in contrast to the usual case, also from the colder one. The work performed by the engine could therefore be larger than the energy taken from the hotter substance alone.